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Common Defects in UV Coatings and Their Causes
Release time:
2026-03-05 07:15
UV coatings are widely used across numerous industrial sectors due to their rapid curing, environmental friendliness, and energy efficiency. However, during actual coating operations, various film defects may arise as a result of material properties, process control, or environmental factors. Understanding the manifestations and root causes of these defects enables the implementation of targeted measures in both production and application processes, thereby enhancing coating quality.
I. Surface Sagging
Sagging manifests as tear-drop– or curtain-like raised streaks on the coating film after it has cured on a vertical surface, typically occurring at the edges of the workpiece or in recessed areas. This phenomenon is usually associated with low paint viscosity, excessive single-coat film thickness, improper solvent evaporation rates, or suboptimal spray application parameters, such as spray gun distance and paint output. In vertical-surface coating, inadequate sag resistance can cause the coating to flow downward under the influence of gravity.
II. Pinholes and Bubbles
Pinholing refers to the appearance of numerous tiny pores on the coating film surface, resembling pinpricks; it is typically caused by air bubbles entrained in the coating that fail to escape before curing. Common causes include excessive coating viscosity, incorporation of air during dispersion, rapid solvent evaporation leading to premature surface skinning, or improper temperature control during the infrared leveling stage. An excessively thick coat can also exacerbate this defect.
III. Uneven Gloss and Hazing
After the coating film has cured, the surface gloss may fall short of expectations, or localized whitening and hazy, foggy mottling may occur—conditions that are particularly common in high-gloss topcoats. These issues can stem from mismatches between the resin and fillers in the formulation, inadequate curing conditions (such as insufficient UV intensity), uneven application, or differences in the absorbency of the substrate. Residual solvents or incomplete curing can also lead to reduced gloss.
IV. Shrink Holes and Fish Eyes
Shrinkage defects manifest as circular or elliptical depressions on the coating surface, with slightly raised edges that resemble a fish eye. These defects typically arise from trace amounts of incompatible contaminants—such as oil, moisture, or silicone-based pollutants—present on the substrate surface or within the coating itself. Failure of the compressed-air filtration system, inadequate cleaning of the workpiece, or insufficient environmental cleanliness can all contribute to the occurrence of such defects.
V. Poor Adhesion
Insufficient adhesion between the cured coating film and the substrate can lead to delamination, paint chipping, and other defects. Possible causes include inadequate substrate surface preparation—such as failure to remove release agents or to perform corona treatment or sanding—poor compatibility between the coating formulation and the substrate, or improper curing conditions that result in insufficient crosslinking. In multi-layer coating systems, intercoat adhesion issues may also arise due to over-curing of the underlying layer or an inappropriate interval between coats.
VI. Incomplete Curing
If the coating film remains tacky, exhibits insufficient hardness, or demonstrates poor solvent resistance after UV irradiation, it indicates that curing has not met expectations. Common causes include inadequate UV lamp power, insufficient irradiation time, poor spectral compatibility between the photoinitiator and the lamp wavelength, or excessive coating thickness that prevents deep-layer exposure to sufficient UV energy. Improper storage of the coating, which can reduce the activity of the photoinitiator, is also a contributing factor.
VII. Residual Odor
The cured coating film still emits a distinct, irritating odor, typically due to incomplete reaction of volatile components in the coating or insufficient curing depth. If the formulation contains high-boiling-point thinners or unreacted monomers, these may be slowly released after curing. In addition, inadequate exhaust ventilation from the application equipment can lead to odor accumulation.
VIII. Bottoming Phenomenon
In multi-layer coating systems, active diluents or solvents in the topcoat can penetrate and swell the underlying cured film, resulting in surface wrinkling, blistering, or localized film loss. This issue is often attributable to poor compatibility between coating formulations, inadequate control of intercoat cure levels, or insufficient curing of the primer layer.
9. Yellowing of the Coating Film
After curing or during service, the coating film may exhibit yellowing, which is particularly pronounced in white or light-colored systems. This yellowing can result from the degradation products of photoinitiators, insufficient thermal stability of the resin system, or prolonged exposure to ultraviolet radiation and elevated temperatures. Optimizing formulation design and curing conditions can help mitigate the tendency toward yellowing.
X. Summary
Various defects that arise in the application of UV coatings are often the result of the combined effects of coating properties, application processes, substrate condition, and curing conditions. By standardizing substrate preparation, optimizing coating parameters, ensuring stable operation of curing equipment, and making appropriate adjustments to the formulation, these defects can be effectively reduced. Low defect rates enhance coating quality and product appearance.
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| Bossin Related Product Recommendations – 3C Coatings | ||
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| B-102 | Bisphenol A epoxy acrylate | High hardness, high gloss, excellent chemical resistance, contains 15% TMPTA. |
| B-151 | Modified epoxy acrylate | Low halogen, yellowing resistance, excellent plating performance, and strong adhesion. |
| B-165 | Modified epoxy acrylate | Good flexibility and strong adhesion |
| B-216 | Aliphatic polyurethane acrylate | Fast curing, high build, and excellent toughness |
| B-368 | Aliphatic polyurethane acrylate | Good toughness, excellent leveling, excellent bend resistance, and excellent heat resistance. |
| B-574C | Polyester acrylate | Low viscosity, low odor, excellent wettability, suitable for LED UV |
| B-601 | Aromatic Polyurethane Acrylate | High hardness, scratch resistance, chemical resistance, and excellent cost performance. |
| B-6019 | Special functional group acrylate | Excellent leveling, excellent wetting, boil-resistant, and excellent color development. |
| B-609 | Aliphatic polyurethane acrylate | Fast curing, high hardness, scratch resistance, and chemical resistance. |
| B-615A | Aliphatic polyurethane acrylate | Fast curing, good toughness, wear resistance, and chemical resistance. |
| B-619W | Aliphatic polyurethane acrylate | Fast curing, high hardness, good toughness, wear resistance, and chemical resistance. |
| B-6380N | Special functional group acrylate | Excellent adhesion, strong hiding power, and improved paint film appearance. |
| B-919B | Aliphatic polyurethane acrylate | Fast curing, high hardness, excellent toughness, and outstanding chemical and wear resistance. |
| Matte | ||
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| B-572 | Polyester acrylate | Low viscosity, low odor, excellent wettability, suitable for LED UV |
| B-650A | Aliphatic polyurethane acrylate | Low viscosity, excellent matting effect, fast curing, and good wettability. |
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| B-868H | Organosilicon UV-Curable Resin | Excellent leveling, smooth finish, fast curing, and stain resistance. |
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| B-6210 | Aliphatic polyurethane acrylate | Low viscosity, chemical resistance, environmental resistance, and dual photothermal curing |
| B-6263 | Special functional group acrylate | Fast curing, high build, boil-resistant, and excellent toughness. |
| B-916 | Aliphatic polyurethane acrylate | Low viscosity, solvent resistance, chemical resistance, and steel-wool resistance. |
| B-919B | Aliphatic polyurethane acrylate | Fast curing, high hardness, excellent toughness, and outstanding chemical and wear resistance. |
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| B-910A2 | Aliphatic polyurethane acrylate | Low viscosity, yellowing resistance, chemical resistance, and steel-wool resistance. |
| B-916 | Aliphatic polyurethane acrylate | Low viscosity, solvent resistance, chemical resistance, and steel-wool resistance. |
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| B-548 | Polyester acrylate | Withstands high temperatures of 250–280°C |
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| B-151 | Modified epoxy acrylate | Low halogen, yellowing resistance, excellent plating performance, and strong adhesion. |
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| Single Product Recommendation | ||
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BM3231 (TMPTA) | Trimethylolpropane triacrylate | High crosslink density, high hardness, high gloss, and excellent wear resistance. |
BM3235 (PET3A) | Pentaerythritol triacrylate | Fast curing, high crosslink density, high hardness, and excellent chemical resistance. |
BM3380 (3EO-TMPTA) | Ethoxylated trimethylolpropane triacrylate | More flexible and less irritating than TMPTA. |
BM4241 (DiTMPTA-80) | Bis(2-hydroxyethyl)propane tetraacrylate | High crosslink density, high hardness, chemical and wear resistance, and water resistance. |
BM4242 (Di-TMPTA) | Bis(3-hydroxypropyl) tetraacrylate | High crosslink density, high hardness, chemical and wear resistance, and water resistance. |
BM6261 (DPHA-80) | Dipentaerythritol hexaacrylate | High crosslink density, high hardness, chemical and wear resistance, and water resistance. |
BM6263 (DPHA-90) | Dipentaerythritol hexaacrylate | High crosslink density, high hardness, chemical and wear resistance, and water resistance. |
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