How to Choose Raw Materials for UV Wood Coatings (Part 1)


The performance of UV wood coatings fundamentally depends on the selection and formulation of raw materials. Among the various components that make up UV wood coatings, resins and photoinitiators are the core ingredients that determine the coating’s basic properties and curing performance. As film‑forming substances, the chemical structure of resins directly influences the hardness, flexibility, adhesion, chemical resistance, and weathering resistance of the cured coating. Photoinitiators, on the other hand, are the key initiators of the curing reaction: under ultraviolet light irradiation, they absorb light energy and generate active species that trigger polymerization and crosslinking in the resin. Selecting these two types of raw materials correctly is the primary step in designing high‑performance UV wood coating formulations.

1. Resin

Resin is the largest component in UV wood coatings, typically accounting for 50% to 80% of the total formulation, and serves as the film‑forming substance that determines the fundamental properties of the coating. The chemical structure and molecular weight distribution of the resin directly influence the coating’s hardness, flexibility, adhesion, chemical resistance, and weathering performance.

Depending on their chemical structures, resins used in UV wood coatings are mainly divided into the following categories:

1. Epoxy acrylate

Propylene glycol epoxy acrylate is produced by reacting epoxy resin with acrylic acid and boasts numerous advantages. After curing, the resulting coating film exhibits high hardness, effectively resisting scratches and impacts during everyday use while providing robust protection for wood surfaces. At the same time, it offers excellent chemical resistance, exhibiting strong resilience against common acids, alkalis, solvents, and other corrosive substances, making it highly resistant to corrosion. In addition, propylene glycol epoxy acrylate cures rapidly and exhibits excellent adhesion, adhering tightly to wood surfaces and remaining firmly in place without easily peeling off. However, its flexibility is relatively limited; when subjected to significant external impact, the coating film may crack. Consequently, it is often used for coating applications on flooring, furniture countertops, and other areas where high hardness and superior chemical resistance are required.

2. Polyurethane Acrylate

Polyurethane acrylate combines the properties of both polyurethane and acrylate. It boasts excellent flexibility, allowing it to accommodate the expansion and contraction of wood caused by changes in temperature and humidity, thereby preventing cracking or peeling of the paint film. Its abrasion resistance is also outstanding; even after prolonged use and friction, the paint film remains intact. Moreover, polyurethane acrylate exhibits exceptional yellowing resistance—under ultraviolet light, it is unlikely to discolor, ensuring that wooden furniture retains its aesthetic appeal over the long term. It is widely used in the coating of high‑end furniture, wooden crafts, and other wood products that demand both superior flexibility and a premium appearance.

3. Polyester Acrylates

Polyester acrylates exhibit excellent flexibility and wettability, providing superior wetting performance on wood surfaces. They can penetrate deep into the wood grain, ensuring strong adhesion. With their outstanding pigment dispersibility, they serve as an ideal base resin for formulating tinted paints, enabling pigments to be evenly dispersed throughout the coating and guaranteeing vibrant, uniform color in the paint film. At the same time, their moderate curing speed facilitates control over leveling during application, resulting in a smooth and even paint film surface.

2. Photoinitiators

Photoinitiators are the key component that enables UV wood coatings to undergo photopolymerization. Although they typically account for only 1% to 5% of the formulation, the selection of photoinitiators directly determines the efficiency and quality of the curing process.

1. Types: Based on their differing mechanisms for generating active species, photoinitiators are primarily divided into two major categories: radical‑type and cationic‑type. Radical‑type photoinitiators are the most widely used and can be further classified into two subtypes: cleavage‑type and hydrogen‑abstraction‑type. Cleavage‑type photoinitiators, such as benzoin ethers and benzoyl ketones, undergo direct cleavage upon excitation to generate free radicals; hydrogen‑abstraction‑type photoinitiators, such as benzophenones, must be used in conjunction with amine co‑initiators to produce free radicals via hydrogen abstraction reactions.

2. Light Source Matching: The primary principle is to ensure that the absorption spectrum of the light source is properly matched. Different wavelengths of ultraviolet light require photoinitiators that correspond to their respective absorption peaks. Traditional mercury lamps have a relatively broad spectral range, making them compatible with a variety of photoinitiators; in contrast, LED‑UV light sources emit light at highly concentrated wavelengths, so only photoinitiators that are specifically matched to these wavelengths can achieve efficient curing.

Balancing curing depth with surface drying performance is another critical consideration. In thick-coat or colored-paint systems, both surface curing and deep‑layer curing must be taken into account. Surface curing requires that the photoinitiator effectively absorbs light energy at the coating’s surface to prevent oxygen inhibition from causing tackiness; deep‑layer curing, on the other hand, demands that ultraviolet light can penetrate all the way to the bottom of the coating, meaning the photoinitiator should not exhibit overly strong absorption at specific wavelengths. Employing a formulation of photoinitiators with differing absorption characteristics is an effective approach to achieving uniform curing from the surface to the depths.

III. Summary

The selection of resins and photoinitiators is the foundation of UV wood coating formulation design. Resin selection must be based on the performance requirements—such as hardness, flexibility, and yellowing resistance—specific to the application scenario, with appropriate choices made or formulations optimized across different resin types. When choosing photoinitiators, key considerations include compatibility with the light source, their impact on curing depth and surface drying performance, as well as compliance with environmental residue standards. Through the scientific selection of these two core raw materials, a solid foundation can be laid at the formulation level for the optimal performance of UV wood coatings.

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Boxing Recommended Products – UV Wood Coatings

Putty primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, containing 20% TPGDA.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective.

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost performance.

Sanding Primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, containing 20% TPGDA.

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective.

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost performance.

Primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-02

Phosphate ester acrylate

Enhance adhesion to substrates such as metal, glass, and plastic.

B-05

Phosphate ester acrylate

Enhance adhesion to substrates such as metal, glass, and plastic.

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, containing 20% TPGDA.

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion.

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost performance.

B-535

Polyester acrylate

Good adhesion, fast curing, excellent flexibility, and yellowing resistance.

B-546

Polyester acrylate

Good adhesion, fast curing, and excellent flexibility.

White primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, containing 20% TPGDA.

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective.

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost performance.

B-529

Polyester acrylate

Good adhesion, low shrinkage, and excellent resin compatibility.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting.

Glossy topcoat

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, containing 20% TPGDA.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion.

B-21C

Active amine photoinitiator

Low color, antioxidant and polymerization inhibitor, enhanced curing rate

B-301

Aromatic Polyurethane Acrylate

Fast curing, good toughness, and excellent sandability.

B-302

Aromatic Polyurethane Acrylate

Fast curing, high strength, good toughness, and excellent grindability.

B-574C

Polyester acrylate

Low viscosity, low odor, good wettability, suitable for LED UV applications.

B-601

Aromatic Polyurethane Acrylate

High hardness, scratch resistance, chemical resistance, and high cost performance.

B-609

Aliphatic polyurethane acrylate

Fast curing, high hardness, scratch resistance, and chemical resistance.

B-868

Organosilicon Photocurable Resin

Good leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon Photocurable Resin

Good leveling, smooth finish, fast curing, and stain resistance.

B-910A2

Aliphatic polyurethane acrylate

Low viscosity, yellowing resistance, chemical resistance, and steel wool resistance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and abrasion resistance.

Matte finish paint

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-21C

Active amine photoinitiator

Low color, antioxidant and polymerization inhibitor, enhanced curing rate

B-328M

Aliphatic polyurethane acrylate

Low gloss, low viscosity, good wettability, pleasant to the touch.

B-328R

Aliphatic polyurethane acrylate

Low gloss, excellent matting effect, good wetting properties, and a fine, smooth hand feel.

B-333

Aliphatic polyurethane acrylate

Low viscosity, good matting effect, excellent wettability, and good flexibility.

B-572

Polyester acrylate

Low viscosity, low odor, good wettability, suitable for LED UV applications.

B-650A

Aliphatic polyurethane acrylate

Low viscosity, good matting effect, fast curing, and excellent wettability.

B-868

Organosilicon Photocurable Resin

Good leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon Photocurable Resin

Good leveling, smooth finish, fast curing, and stain resistance.

B-910A2

Aliphatic polyurethane acrylate

Low viscosity, yellowing resistance, chemical resistance, and steel wool resistance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and abrasion resistance.

Bright white paint

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, containing 20% TPGDA.

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-301

Aromatic Polyurethane Acrylate

Fast curing, good toughness, and excellent sandability.

B-302

Aromatic Polyurethane Acrylate

Fast curing, high strength, good toughness, and excellent grindability.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting.

B-574C

Polyester acrylate

Low viscosity, low odor, good wettability, suitable for LED UV applications.

B-601

Aromatic Polyurethane Acrylate

High hardness, scratch resistance, chemical resistance, and high cost performance.

B-868

Organosilicon Photocurable Resin

Good leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon Photocurable Resin

Good leveling, smooth finish, fast curing, and stain resistance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and abrasion resistance.

Adherent

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-05

Phosphate ester acrylate

Enhance adhesion to substrates such as metal, glass, and plastic.

B-509B

Polyester acrylate

Good adhesion, excellent flexibility, and excellent pigment wetting.

B-531

Polyester acrylate

Good adhesion, impact resistance, excellent flexibility, and yellowing resistance.

B-535

Polyester acrylate

Good adhesion, fast curing, excellent flexibility, and yellowing resistance.

B-546

Polyester acrylate

Good adhesion, fast curing, and excellent flexibility.

B-590

Polyester acrylate

Good adhesion, fast curing, and excellent pigment wetting.

Filler type

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, containing 20% TPGDA.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective.

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost performance.

B-529

Polyester acrylate

Good adhesion, low shrinkage, and excellent resin compatibility.

Retouch color

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-560

Polyester acrylate

Fast curing and excellent pigment wetting.

Hardened

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, containing 20% TPGDA.

B-301

Aromatic Polyurethane Acrylate

Fast curing, good toughness, and excellent sandability.

B-302

Aromatic Polyurethane Acrylate

Fast curing, high strength, good toughness, and excellent grindability.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting.

B-574C

Polyester acrylate

Low viscosity, low odor, good wettability, suitable for LED UV applications.

B-601

Aromatic Polyurethane Acrylate

High hardness, scratch resistance, chemical resistance, and high cost performance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and abrasion resistance.

Matte

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-328M

Aliphatic polyurethane acrylate

Low gloss, low viscosity, good wettability, pleasant to the touch.

B-328R

Aliphatic polyurethane acrylate

Low gloss, excellent matting effect, good wetting properties, and a fine, smooth hand feel.

B-329D

Aliphatic polyurethane acrylate

Low irritation, low viscosity, excellent wettability, and a pleasant hand feel.

B-333

Aliphatic polyurethane acrylate

Low viscosity, good matting effect, excellent wettability, and good flexibility.

B-650A

Aliphatic polyurethane acrylate

Low viscosity, good matting effect, fast curing, and excellent wettability.

Solid-color paint

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-519

Self‑Curing Polyester Acrylate

Self‑initiated Photocuring Performance

B-530

Polyester acrylate

Low viscosity, excellent hydrophobicity, thixotropic properties, and improved ink mist.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting.

Yellowing resistance

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-431

Alicyclic Specialty Acrylates

Yellowing resistance, excellent wettability, low viscosity, fast curing.

Spray coating

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

Roller Coating

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-100

Bisphenol A epoxy acrylate

High hardness, high gloss, excellent chemical resistance, and rich body.

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, containing 20% TPGDA.

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective.

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost performance.

Solvent-free spraying

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-251

Aromatic Polyurethane Acrylate

Fast curing, excellent flexibility, and good wetting performance with black ink pigments.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective.

B-574C

Polyester acrylate

Low viscosity, low odor, good wettability, suitable for LED UV applications.

LED-UV

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, containing 20% TPGDA.

B-21C

Active amine photoinitiator

Low color, antioxidant and polymerization inhibitor, enhanced curing rate

B-241

Aliphatic polyurethane acrylate

Fast matting speed, excellent skin feel, and yellowing resistance.

B-27

Active amine photoinitiator

Low color, benzene-free, low odor, antioxidant and anti‑polymerization.

B-570

Polyester acrylate

Low viscosity, benzene‑free, low odor, suitable for LED UV.

B-574

Polyester acrylate

Benzene-free, low odor, and VOC levels meet cigarette packaging standards.

B-574C

Polyester acrylate

Low viscosity, low odor, good wettability, suitable for LED UV applications.

Excimer lamp

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-241

Aliphatic polyurethane acrylate

Fast matting speed, excellent skin feel, and yellowing resistance.

Skin feel

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, containing 20% TPGDA.

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion.

B-241

Aliphatic polyurethane acrylate

Fast matting speed, excellent skin feel, and yellowing resistance.

B-328M

Aliphatic polyurethane acrylate

Low gloss, low viscosity, good wettability, pleasant to the touch.

B-328R

Aliphatic polyurethane acrylate

Low gloss, excellent matting effect, good wetting properties, and a fine, smooth hand feel.

B-574C

Polyester acrylate

Low viscosity, low odor, good wettability, suitable for LED UV applications.

B-868

Organosilicon Photocurable Resin

Good leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon Photocurable Resin

Good leveling, smooth finish, fast curing, and stain resistance.

Single-Component Recommendation

Product Model/English Abbreviation

Product Name/Product Type

Product Features

BM2223/TPGDA

Di(propylene glycol) diacrylate

Good flexibility and low volatility.

BM2224/EO-HDDA

Ethoxylated 1,6-hexanediol diacrylate

Good adhesion to plastics, excellent dilutability, and low volatility.

BM3231/TMPTA

Trimethylolpropane triacrylate

High crosslink density, high hardness, high gloss, and excellent wear resistance.

BM3235/PET3A

Pentaerythritol triacrylate

Fast curing, high crosslink density, high hardness, and excellent chemical resistance.

BM3380/3EO-TMPTA

Ethoxylated trimethylolpropane triacrylate

More flexible and less irritating than TMPTA.

BM6261/DPHA-80

Dipentaerythritol hexaacrylate

High crosslink density, high hardness, chemical and abrasion resistance, and water resistance.

BM6263/DPHA-90

Dipentaerythritol hexaacrylate

High crosslink density, high hardness, chemical and abrasion resistance, and water resistance.

 

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