Common Defects in UV Wood Coatings (Part 6)


The essence of clear coating lies in providing a protective layer for wood products while fully showcasing the wood’s natural grain and color. However, in the practical application of UV wood coatings, a defect known as “whitening” often undermines this ideal outcome. After curing, the coating film loses its intended clarity and transparency, developing a milky-white, hazy opacity that resembles a delicate mist or sheer veil. Mild whitening slightly blurs the wood grain, whereas severe whitening renders the film completely opaque, entirely obscuring the grain and giving the surface the appearance of frosted glass. Under illumination, whitened areas exhibit diffuse reflection, forfeiting the depth and luster characteristic of a well-cured coating; yet the surface remains smooth to the touch, creating a stark contrast between visual and tactile sensations. Whitening is often accompanied by reduced film hardness, significantly compromising protective performance, and is the result of complex interactions among multiple factors, including moisture interference, residual solvents, and the precipitation of film-forming components.

I. Description of the Phenomenon

After curing, the clear varnish film loses its intended clarity and transparency, developing a milky-white, hazy opacity. This cloudiness is evenly distributed throughout the entire film, giving it the appearance of being veiled in a thin mist or sheer white gauze. Mild whitening manifests as a slight reduction in film transparency and a subtle blurring of the wood grain; severe whitening, however, renders the film completely opaque, completely obscuring the wood grain and resulting in a surface that resembles frosted glass. Under illumination, the whitened areas exhibit diffuse reflection, thereby losing the deep richness and luster characteristic of a properly cured varnish film. To the touch, the film surface remains smooth, creating a striking contrast between the visual haziness and the tactile smoothness. Whitening is often accompanied by a decrease in film hardness, such that even a light scratch with a fingernail may leave a mark.

II. In-depth Analysis of the Root Causes

1. Influence of Moisture

(1) Excessive wood moisture content: When wood contains a large amount of free water, after painting—particularly during the curing and heating process—water vapor escapes outward. However, some of the vapor that does not have time to escape becomes trapped within the rapidly forming paint film. Because water and the paint film have different refractive indices, these tiny water droplets create countless refractive interfaces inside the film, causing light to undergo diffuse reflection and resulting in a milky-white, hazy appearance on the macroscopic scale.

(2) Excessive ambient humidity: In high-humidity environments, the wet film absorbs substantial amounts of moisture from the air during the leveling process. This absorbed moisture can emulsify with or become miscible in the paint formulation, leading to whitening upon curing.

2. Incomplete solvent evaporation

During the application of thick coatings, the solvents in the top layer evaporate rapidly, increasing the resin concentration and viscosity. Meanwhile, the solvents in the underlying layers are trapped and cannot escape smoothly. These residual solvents form tiny voids within the paint film; when the voids reach a certain size, they scatter light, resulting in haze. This whitening is often accompanied by a soft, undercured paint film with insufficient hardness.

3. Analysis results

In certain cases, specific additives or fillers in UV coatings may undergo flocculation or precipitation under application conditions, resulting in an uneven microscale particle distribution and consequently reduced transparency.

III. Conclusion

The essence of whitening lies in the diffuse reflection of light caused by refractive interfaces within the paint film, a phenomenon rooted in the film’s microstructural non-uniformity. When wood moisture content is excessively high or ambient humidity is too great, water vapor becomes trapped within the rapidly curing paint layer, forming countless microscopic water droplets. The refractive-index contrast between these droplets and the paint itself gives rise to a milky-white, hazy turbidity. Incomplete solvent evaporation can also lead to the formation of minute voids within the paint film, which scatter light and reduce transparency. Furthermore, flocculation and precipitation of additives or fillers in the coating can disrupt the film’s microscopic homogeneity. Together, these factors interfere with the straight-line transmission of light at various levels, causing what was once a clear paint film to take on a white haze and obscuring the wood’s natural beauty beneath the resulting cloudiness.

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Bossin Recommended Products – UV Wood Coatings

Putty primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

Sanding primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

Apply primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-02

Phosphate ester acrylate

Enhances adhesion to substrates such as metal, glass, and plastic.

B-05

Phosphate ester acrylate

Enhances adhesion to substrates such as metal, glass, and plastic.

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

B-535

Polyester acrylate

Excellent adhesion, rapid curing, good flexibility, and yellowing resistance.

B-546

Polyester acrylate

Good adhesion, fast curing, and excellent flexibility.

White primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

B-529

Polyester acrylate

Good adhesion, low shrinkage, and excellent resin compatibility.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

Gloss topcoat

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion

B-21C

Active amine photosensitizing promoter

Low color number, antioxidant and polymerization inhibitor, and enhanced curing rate

B-301

Aromatic Polyurethane Acrylate

Fast curing, good toughness, and excellent grindability.

B-302

Aromatic Polyurethane Acrylate

Fast curing, high strength, good toughness, and excellent grindability.

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-601

Aromatic Polyurethane Acrylate

High hardness, scratch resistance, chemical resistance, and excellent cost performance.

B-609

Aliphatic polyurethane acrylate

Fast curing, high hardness, scratch resistance, and chemical resistance.

B-868

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-910A2

Aliphatic polyurethane acrylate

Low viscosity, yellowing resistance, chemical resistance, and steel-wool resistance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and wear resistance.

Matte topcoat

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-21C

Active amine photosensitizing promoter

Low color number, antioxidant and polymerization inhibitor, and enhanced curing rate

B-328M

Aliphatic polyurethane acrylate

Low gloss, low viscosity, excellent wettability, and a pleasant hand feel.

B-328R

Aliphatic polyurethane acrylate

Low gloss, excellent matting, good wetting, and a fine, smooth, and silky hand feel.

B-333

Aliphatic polyurethane acrylate

Low viscosity, excellent matting effect, good wetting properties, and excellent flexibility.

B-572

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-650A

Aliphatic polyurethane acrylate

Low viscosity, excellent matting effect, fast curing, and good wettability.

B-868

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-910A2

Aliphatic polyurethane acrylate

Low viscosity, yellowing resistance, chemical resistance, and steel-wool resistance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and wear resistance.

Bright White Finish

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-301

Aromatic Polyurethane Acrylate

Fast curing, good toughness, and excellent grindability.

B-302

Aromatic Polyurethane Acrylate

Fast curing, high strength, good toughness, and excellent grindability.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-601

Aromatic Polyurethane Acrylate

High hardness, scratch resistance, chemical resistance, and excellent cost performance.

B-868

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and wear resistance.

Adherent

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-05

Phosphate ester acrylate

Enhances adhesion to substrates such as metal, glass, and plastic.

B-509B

Polyester acrylate

Good adhesion, good flexibility, and excellent pigment wetting.

B-531

Polyester acrylate

Good adhesion, impact resistance, excellent flexibility, and yellowing resistance.

B-535

Polyester acrylate

Excellent adhesion, rapid curing, good flexibility, and yellowing resistance.

B-546

Polyester acrylate

Good adhesion, fast curing, and excellent flexibility.

B-590

Polyester acrylate

Excellent adhesion, rapid curing, and good pigment wetting.

Filler type

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

B-529

Polyester acrylate

Good adhesion, low shrinkage, and excellent resin compatibility.

Color correction

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

Harden

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-301

Aromatic Polyurethane Acrylate

Fast curing, good toughness, and excellent grindability.

B-302

Aromatic Polyurethane Acrylate

Fast curing, high strength, good toughness, and excellent grindability.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-601

Aromatic Polyurethane Acrylate

High hardness, scratch resistance, chemical resistance, and excellent cost performance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and wear resistance.

Matte

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-328M

Aliphatic polyurethane acrylate

Low gloss, low viscosity, excellent wettability, and a pleasant hand feel.

B-328R

Aliphatic polyurethane acrylate

Low gloss, excellent matting, good wetting, and a fine, smooth, and silky hand feel.

B-329D

Aliphatic polyurethane acrylate

Low irritation, low viscosity, excellent wettability, and a pleasant feel.

B-333

Aliphatic polyurethane acrylate

Low viscosity, excellent matting effect, good wetting properties, and excellent flexibility.

B-650A

Aliphatic polyurethane acrylate

Low viscosity, excellent matting effect, fast curing, and good wettability.

Solid-color paint

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-519

Self-curing polyester acrylate

Self-initiated photopolymerization performance

B-530

Polyester acrylate

Low viscosity, excellent hydrophobicity, thixotropy, and improved ink misting

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

Yellowing resistance

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-431

Cycloaliphatic Specialty Acrylates

Yellowing resistance, excellent wettability, low viscosity, and fast curing

Dip coating

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

Roll coating

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-100

Bisphenol A epoxy acrylate

High hardness, high gloss, excellent chemical resistance, and high fullness.

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

Solvent-free spraying

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-251

Aromatic Polyurethane Acrylate

Fast curing, excellent flexibility, and good wetting of black ink pigments.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

LED-UV

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-21C

Active amine photosensitizing promoter

Low color number, antioxidant and polymerization inhibitor, and enhanced curing rate

B-27

Active amine photosensitizing promoter

Low color number, benzene-free, low odor, antioxidant and anti-polymerization

B-570

Polyester acrylate

Low viscosity, benzene-free, low odor, suitable for LED UV

B-574

Polyester acrylate

Benzene-free, low odor, and VOC levels meet cigarette pack standards.

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

Excimer lamp

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-241

Aliphatic polyurethane acrylate

Fast curing, excellent skin feel, and yellowing resistance.

Skin feel

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion

B-241

Aliphatic polyurethane acrylate

Fast curing, excellent skin feel, and yellowing resistance.

B-328M

Aliphatic polyurethane acrylate

Low gloss, low viscosity, excellent wettability, and a pleasant hand feel.

B-328R

Aliphatic polyurethane acrylate

Low gloss, excellent matting, good wetting, and a fine, smooth, and silky hand feel.

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-868

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

Single-item recommendation

Product Model/English Abbreviation

Product Name/Product Type

Product Features

BM2223 (TPGDA)

Di(propylene glycol) diacrylate

Good flexibility and low volatility

BM2224 (EO-HDDA)

Ethoxylated 1,6-hexanediol diacrylate

Good adhesion to plastics, good dilutability, and low volatility.

BM3231 (TMPTA)

Trimethylolpropane triacrylate

High crosslink density, high hardness, high gloss, and excellent wear resistance.

BM3235 (PET3A)

Pentaerythritol triacrylate

Fast curing, high crosslink density, high hardness, and excellent chemical resistance.

BM3380 (3EO-TMPTA)

Tripropylene Glycol Triacrylate

More flexible and less irritating than TMPTA.

BM6261 (DPHA-80)

Dipentaerythritol hexaacrylate

High crosslink density, high hardness, chemical and wear resistance, and water resistance.

BM6263 (DPHA-90)

Dipentaerythritol hexaacrylate

High crosslink density, high hardness, chemical and wear resistance, and water resistance.

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