Common Defects in UV Wood Coatings (Part 9)


In the field of wood coatings, UV wood finishes have become the preferred choice for many manufacturers thanks to their rapid curing, environmental friendliness, and high efficiency. They not only impart an aesthetically pleasing appearance to wood products but also provide excellent protective performance. However, in practical applications, UV wood finishes are not always flawless; one of the more challenging issues is brittleness caused by inadequate curing. A brittle coating film not only detracts from the overall aesthetic appeal of the product but also severely compromises its functional performance and durability, posing significant challenges for manufacturers. Therefore, a thorough investigation into the phenomenon of brittleness resulting from poor curing in UV wood coatings—and the underlying causes—is of great practical significance for resolving this problem and enhancing product quality.

I. Description of the Phenomenon

Although the paint film achieves the required hardness after curing, it lacks adequate toughness. When struck or scratched with a sharp object, the film readily develops cracks that radiate outward or form a network pattern. During handling, assembly, or service, even minor impacts can cause chipping at the edges or at the point of impact, leading to flaking and spalling of small fragments. When the workpiece is bent or subjected to compressive deformation, the paint film cracks accordingly, with the fissures typically oriented perpendicular to the direction of the applied load. In subsequent machining operations such as sawing or mortise-and-tenon jointing, the paint film along the cut edges tends to flake off in large pieces. Although the surface gloss of a brittle paint film may appear normal, applying firm pressure with a fingernail will produce a faint cracking sound. Under microscopic examination, a fine network of microcracks can often be observed within the paint film itself.

II. In-depth Analysis of the Root Causes

1. Excessive energy

When the UV energy exceeds the critical threshold required for coating formulation, the crosslink density becomes excessively high, resulting in an over-dense three-dimensional network. In such a network, segmental chain mobility is severely restricted, causing the paint film to lose its ability to absorb and dissipate impact energy, thereby becoming rigid and brittle.

2. Accumulation of Shrinkage Stress

UV curing is the rapid transformation of liquid monomers into a solid polymer, accompanied by volumetric shrinkage. If a single coat is applied too thickly, this volumetric shrinkage cannot be compensated by the flow of the coating film, resulting in substantial tensile internal stresses within the film. Even the slightest external force can then trigger cracking.

When the shrinkage and flexibility of the primer and topcoat are mismatched, shear stress develops at the interface, which can likewise lead to brittle cracking of the topcoat.

3. Formulation Factors

The coating formulation contains an excessively high proportion of rigid components and an insufficient proportion of flexible components, or an excessive amount of crosslinking agents resulting in overly dense crosslinking points.

III. Conclusion

The issue of poor curing and embrittlement in UV wood coatings arises from the combined effects of multiple factors, including UV energy, shrinkage stress, and formulation. From precisely controlling UV energy to prevent excessive crosslinking caused by overintensity, to appropriately optimizing coating thickness to minimize the buildup of shrinkage stress, and further to refining the coating formulation to strike a balance between rigid and flexible components, each step must be handled with meticulous care. Only by comprehensively understanding these influencing factors and implementing practical, effective improvement measures can we effectively address the problem of poor curing and embrittlement in UV wood coatings, ensure the production of paint films with excellent toughness and durability, provide reliable protection for wood products, enhance product competitiveness in the market, and drive the wood coating industry toward higher quality standards.

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Bossin Recommended Products – UV Wood Coatings

Putty primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

Sanding primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

Apply primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-02

Phosphate ester acrylate

Enhances adhesion to substrates such as metal, glass, and plastic.

B-05

Phosphate ester acrylate

Enhances adhesion to substrates such as metal, glass, and plastic.

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

B-535

Polyester acrylate

Excellent adhesion, rapid curing, good flexibility, and yellowing resistance.

B-546

Polyester acrylate

Good adhesion, fast curing, and excellent flexibility.

White primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

B-529

Polyester acrylate

Good adhesion, low shrinkage, and excellent resin compatibility.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

Gloss topcoat

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion

B-21C

Active amine photosensitizing promoter

Low color number, antioxidant and polymerization inhibitor, and enhanced curing rate

B-301

Aromatic Polyurethane Acrylate

Fast curing, good toughness, and excellent grindability.

B-302

Aromatic Polyurethane Acrylate

Fast curing, high strength, good toughness, and excellent grindability.

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-601

Aromatic Polyurethane Acrylate

High hardness, scratch resistance, chemical resistance, and excellent cost performance.

B-609

Aliphatic polyurethane acrylate

Fast curing, high hardness, scratch resistance, and chemical resistance.

B-868

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-910A2

Aliphatic polyurethane acrylate

Low viscosity, yellowing resistance, chemical resistance, and steel-wool resistance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and wear resistance.

Matte topcoat

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-21C

Active amine photosensitizing promoter

Low color number, antioxidant and polymerization inhibitor, and enhanced curing rate

B-328M

Aliphatic polyurethane acrylate

Low gloss, low viscosity, excellent wettability, and a pleasant hand feel.

B-328R

Aliphatic polyurethane acrylate

Low gloss, excellent matting, good wetting, and a fine, smooth, and silky hand feel.

B-333

Aliphatic polyurethane acrylate

Low viscosity, excellent matting effect, good wetting properties, and excellent flexibility.

B-572

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-650A

Aliphatic polyurethane acrylate

Low viscosity, excellent matting effect, fast curing, and good wettability.

B-868

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-910A2

Aliphatic polyurethane acrylate

Low viscosity, yellowing resistance, chemical resistance, and steel-wool resistance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and wear resistance.

Bright White Finish

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-301

Aromatic Polyurethane Acrylate

Fast curing, good toughness, and excellent grindability.

B-302

Aromatic Polyurethane Acrylate

Fast curing, high strength, good toughness, and excellent grindability.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-601

Aromatic Polyurethane Acrylate

High hardness, scratch resistance, chemical resistance, and excellent cost performance.

B-868

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and wear resistance.

Adherent

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-05

Phosphate ester acrylate

Enhances adhesion to substrates such as metal, glass, and plastic.

B-509B

Polyester acrylate

Good adhesion, good flexibility, and excellent pigment wetting.

B-531

Polyester acrylate

Good adhesion, impact resistance, excellent flexibility, and yellowing resistance.

B-535

Polyester acrylate

Excellent adhesion, rapid curing, good flexibility, and yellowing resistance.

B-546

Polyester acrylate

Good adhesion, fast curing, and excellent flexibility.

B-590

Polyester acrylate

Excellent adhesion, rapid curing, and good pigment wetting.

Filler type

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

B-529

Polyester acrylate

Good adhesion, low shrinkage, and excellent resin compatibility.

Color correction

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

Harden

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-301

Aromatic Polyurethane Acrylate

Fast curing, good toughness, and excellent grindability.

B-302

Aromatic Polyurethane Acrylate

Fast curing, high strength, good toughness, and excellent grindability.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-601

Aromatic Polyurethane Acrylate

High hardness, scratch resistance, chemical resistance, and excellent cost performance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and wear resistance.

Matte

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-328M

Aliphatic polyurethane acrylate

Low gloss, low viscosity, excellent wettability, and a pleasant hand feel.

B-328R

Aliphatic polyurethane acrylate

Low gloss, excellent matting, good wetting, and a fine, smooth, and silky hand feel.

B-329D

Aliphatic polyurethane acrylate

Low irritation, low viscosity, excellent wettability, and a pleasant feel.

B-333

Aliphatic polyurethane acrylate

Low viscosity, excellent matting effect, good wetting properties, and excellent flexibility.

B-650A

Aliphatic polyurethane acrylate

Low viscosity, excellent matting effect, fast curing, and good wettability.

Solid-color paint

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-519

Self-curing polyester acrylate

Self-initiated photopolymerization performance

B-530

Polyester acrylate

Low viscosity, excellent hydrophobicity, thixotropy, and improved ink misting

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

Yellowing resistance

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-431

Cycloaliphatic Specialty Acrylates

Yellowing resistance, excellent wettability, low viscosity, and fast curing

Dip coating

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

Roll coating

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-100

Bisphenol A epoxy acrylate

High hardness, high gloss, excellent chemical resistance, and high fullness.

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

Solvent-free spraying

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-251

Aromatic Polyurethane Acrylate

Fast curing, excellent flexibility, and good wetting of black ink pigments.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

LED-UV

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-21C

Active amine photosensitizing promoter

Low color number, antioxidant and polymerization inhibitor, and enhanced curing rate

B-27

Active amine photosensitizing promoter

Low color number, benzene-free, low odor, antioxidant and anti-polymerization

B-570

Polyester acrylate

Low viscosity, benzene-free, low odor, suitable for LED UV

B-574

Polyester acrylate

Benzene-free, low odor, and VOC levels meet cigarette pack standards.

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

Excimer lamp

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-241

Aliphatic polyurethane acrylate

Fast curing, excellent skin feel, and yellowing resistance.

Skin feel

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion

B-241

Aliphatic polyurethane acrylate

Fast curing, excellent skin feel, and yellowing resistance.

B-328M

Aliphatic polyurethane acrylate

Low gloss, low viscosity, excellent wettability, and a pleasant hand feel.

B-328R

Aliphatic polyurethane acrylate

Low gloss, excellent matting, good wetting, and a fine, smooth, and silky hand feel.

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-868

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

Single-item recommendation

Product Model/English Abbreviation

Product Name/Product Type

Product Features

BM2223 (TPGDA)

Di(propylene glycol) diacrylate

Good flexibility and low volatility

BM2224 (EO-HDDA)

Ethoxylated 1,6-hexanediol diacrylate

Good adhesion to plastics, good dilutability, and low volatility.

BM3231 (TMPTA)

Trimethylolpropane triacrylate

High crosslink density, high hardness, high gloss, and excellent wear resistance.

BM3235 (PET3A)

Pentaerythritol triacrylate

Fast curing, high crosslink density, high hardness, and excellent chemical resistance.

BM3380 (3EO-TMPTA)

Tripropylene Glycol Triacrylate

More flexible and less irritating than TMPTA.

BM6261 (DPHA-80)

Dipentaerythritol hexaacrylate

High crosslink density, high hardness, chemical and wear resistance, and water resistance.

BM6263 (DPHA-90)

Dipentaerythritol hexaacrylate

High crosslink density, high hardness, chemical and wear resistance, and water resistance.

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