Analysis of Defects in UV Three-Proof Coatings and Corresponding Countermeasures (Part 4)


In the field of industrial coating, UV three-proof coatings—thanks to their outstanding protective performance—are widely used in various electronic and electrical products, providing substrates with triple protection against moisture, salt spray, and mold. This effectively extends the service life of the products. However, during actual coating processes, the phenomenon of "undercutting" frequently troubles manufacturers. Not only does undercutting spoil the aesthetic appeal of the coating, but it also severely compromises its protective performance, leaving products exposed to harsh environmental conditions and increasing the risk of damage. A thorough analysis of the causes behind undercutting and the exploration of practical, feasible solutions are crucial for ensuring coating quality and enhancing product reliability.

I. Analysis of the Underbite Phenomenon

Biting refers to a phenomenon that occurs during the curing process of UV-resistant three-coat coatings, in which an incompatible chemical reaction takes place between the newly applied coating layer and the primer or previously applied coating layers, causing the primer layer to partially or completely dissolve, soften, or even peel off. Biting can lead to poor adhesion of the underlying coating film, resulting in shrinkage, cracking, and, in severe cases, complete loss of adhesion and subsequent delamination—exposing the substrate directly. This significantly compromises both the aesthetic appearance and protective performance of the coating.

II. Causes of Undercutting

1. Coating formulation issues

The primer has poor compatibility with the UV-resistant topcoat, and the solvent in the topcoat has excessively strong dissolving power, eroding the primer and causing the solvents in the topcoat to dissolve and soften the primer.

2. Coating process issues

If the primer is not fully dry, or if it’s an oxidation-curing or two-component curing type, and the topcoat is applied before the primer has undergone sufficient oxidation and film formation, the solvents in the topcoat can dissolve and soften the primer. Alternatively, if the topcoat is applied by brushing too slowly or with excessive and repeated brushings, this can also lead to similar issues.

The thickness of the coating and the leveling time are also important factors that influence undercutting. If the coating is too thick or the leveling time is excessively long, it may result in an uneven paint surface, thereby increasing the risk of undercutting.

3. Improper solvent selection

The strength of the solvent can affect the coating process. If the solvent is too strong, it may erode the substrate, leading to undercutting.

4. Improper baking process

If the product is baked immediately after spraying and the baking temperature is too high, the solvent may evaporate too rapidly, causing the paint film to “bite into” the substrate.

III. Solution

1. Selection and Matching of Primer and Topcoat

When selecting a UV-resistant three-proof coating, refer to the coating manufacturer’s recommendations or conduct compatibility tests. It is important to choose a primer that is highly compatible with the UV-resistant three-proof coating, ensuring that their chemical compositions do not erode each other.

Before applying the UV-resistant three-proof coating, ensure that the primer has fully cured or dried and reached its specified curing time, forming a stable coating film. Then apply the topcoat to prevent reactive functional groups in the primer from reacting with the topcoat.

2. Optimization of Coating Process

Adjust the formulation of the UV-resistant three-proof coating to avoid using solvents or additives that could dissolve the primer. Additionally, enhance the compatibility and stability of the coating by adding appropriate additives or modifying the resin structure.

Control the thickness and leveling time of the coating to ensure that the UV three-proof paint is evenly applied over the primer and fully reacts with it. At the same time, pay attention to selecting the appropriate spraying method and adjusting the parameters carefully to avoid applying too thick a coat or creating air bubbles.

3. Control the baking process

Ensure that the baking temperature and time are appropriate, avoiding excessively high or low baking temperatures that could result in insufficient chemical reaction between the UV three-proof coating and the primer.

IV. Summary

The "biting-through" phenomenon is a common and challenging issue in the application of UV-resistant three-coat systems, posing a serious threat to coating quality and product performance. Through a systematic analysis of its causes, we have identified that multiple factors—including coating formulation, application process, solvent selection, and baking procedure—can all contribute to the occurrence of biting-through. The solutions proposed to address these causes—such as rationally selecting and matching primer and topcoat formulations, optimizing coating processes, and precisely controlling the baking procedure—provide practical and effective pathways for preventing and resolving the biting-through problem.

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