How to Address Defects in UV 3C Coatings (Part 3)


In the practical production of UV 3C coatings, bubbles and pinholes are common defects that compromise coating density and surface smoothness. Bubbles appear as circular blisters of varying sizes on the coating surface, while pinholes are the tiny depressions left behind after these bubbles rupture. To address these defects, appropriate measures must be implemented across several stages, including compressed air quality, control of coating film thickness, substrate condition management, and coating degassing. This paper outlines methods for mitigating bubble and pinhole defects by focusing on air‑source purification, adjustments to the coating application process, substrate preparation, and coating formulation management.

I. Purification and Treatment of Compressed Air

Moisture and oil contaminants in compressed air are major sources of bubble defects. During treatment, the compressed‑air system should be equipped with efficient drying and filtration equipment. Air dryers may be either refrigerated or desiccant types, ensuring that the dew point of the compressed air meets process requirements. Oil‑water separators should be installed at appropriate locations along the compressed‑air piping and drained regularly to remove accumulated condensate.

Precision filters should have their filter elements replaced regularly based on operating conditions to maintain filtration performance. When the pressure differential across the filter increases, it indicates that the filter element is clogged and should be replaced promptly. Compressed air piping should avoid materials prone to rusting to prevent rust particles from entering the airflow. Regularly monitor compressed air quality, including moisture and oil content, to ensure compliance with coating requirements.

II. Control of Spray Coating Film Thickness

Excessive coating thickness is a major cause of bubbles and pinholes. When applying the coating, carefully control the spray parameters to prevent excessive build-up in a single pass. Maintain a consistent gun travel speed; avoid slowing down too much, which can lead to paint buildup. Adjust the flow rate according to the part’s geometry and coating requirements—do not set it too high.

During spraying, maintain an appropriate distance between the spray gun and the workpiece to prevent excessive local film thickness caused by too close a proximity. For workpieces with complex geometries, adjust the spray pattern to ensure uniform coating across all areas. Film‑thickness measurement should be integrated into routine quality control, and any deviations should prompt timely adjustments to the spraying parameters.

For products requiring a thicker coating, apply multiple thin coats instead of a single thick coat. Cure after each application before applying the next layer to prevent excessive thickness in any one coat, which could impede gas escape.

III. Management of Substrate Condition

Pores and moisture on the substrate surface are among the primary causes of bubbles and pinholes. Proper pretreatment of the substrate is essential during application. For substrates with microscopic pores, a primer with excellent sealing properties can be used to seal these pores, thereby minimizing the accumulation of gases within them.

The moisture content of the substrate should be maintained within an appropriate range. Substrates with high hygroscopicity should be stored in a dry environment and may undergo drying prior to use. The substrate surface must be kept clean and dry; after cleaning, it must be thoroughly dried before proceeding to the coating process.

IV. Defoaming Treatment of Coatings

Air and solvents entrained in the coating are among the primary sources of bubbles. Prior to application, the coating should be allowed to stand undisturbed for thorough degassing. Air may also be introduced during mixing and pumping; allowing the coating to settle for a period before coating enables bubbles to escape naturally.

For coatings with high viscosity, vacuum degassing can be employed to rapidly remove internal air bubbles under negative pressure. The degassing time and vacuum level should be optimized according to the coating’s properties to prevent excessive degassing, which could lead to solvent evaporation or changes in the formulation.

The coating delivery piping should be kept tightly sealed to prevent air from being drawn in at the joints. The pumping pressure of the coating should be appropriately adjusted to avoid excessive pressure that could cause air entrainment.

V. Adjustment of Curing Conditions

Excessive curing speed may prevent gases from escaping before the material fully cures. During processing, curing conditions can be adjusted as needed. For bubble formation caused by rapid surface curing, the UV irradiation intensity can be reduced or the irradiation time shortened to allow sufficient time for gas to escape prior to complete cure.

For production lines equipped with conveyor‑type curing systems, the conveyor speed can be adjusted appropriately to extend the leveling time of the coating prior to curing. The energy output of the curing lamps should remain stable to prevent fluctuations in curing speed caused by variations in energy levels.

VI. Integrated Process Control

Addressing bubble and pinhole defects requires comprehensive control across multiple process steps. Regarding the air supply, ensure that the compressed air is dry and clean; for coating, maintain an appropriate film thickness to avoid excessive buildup by employing multiple thin coats; on the substrate side, manage moisture content and apply suitable sealing treatments; in the coating formulation, thoroughly degas the material and standardize transfer operations; and during curing, carefully regulate both the cure rate and the energy input.

The control of each process step is interrelated, and adjustments should be made with a holistic consideration. In actual production, the primary sources of defects can be identified by analyzing the distribution patterns and morphologies of bubbles and pinholes, allowing for targeted reinforcement of controls at the corresponding stages.

VII. Conclusion

Addressing bubble and pinhole defects involves multiple stages, including compressed air purification, coating film‑thickness control, substrate condition management, paint deaeration, and adjustments to curing conditions. By ensuring that the compressed air is dry and clean, controlling coating thickness to prevent excessive buildup, managing substrate moisture content and surface condition, standardizing paint deaeration and delivery, and fine-tuning the curing rate to allow sufficient time for gases to escape, the occurrence of bubbles and pinholes can be effectively minimized. Optimizing each of these steps requires coordinated efforts and a holistic consideration of equipment status, material properties, and process requirements to achieve an ideally satisfactory outcome.

Disclaimer: The above content has been compiled from publicly available sources and is provided for reference only. If any infringement occurs, please contact us, and we will address it promptly.

Bosheng Related Product Recommendations – 3C Coatings

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B-102

Bisphenol A epoxy acrylate

High hardness, high gloss, chemical resistance, contains 15% TMPTA.

B-151

Modified epoxy acrylate

Low halogen, yellowing-resistant, excellent plating performance, and strong adhesion.

B-165

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B-216

Aliphatic polyurethane acrylate

Fast curing, high fullness, and excellent toughness.

B-368

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B-574C

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Low viscosity, low odor, excellent wettability, suitable for LED UV.

B-601

Aromatic polyurethane acrylate

High hardness, scratch resistance, chemical resistance, and excellent cost-effectiveness.

B-6019

Special functional group acrylate

Good leveling, excellent wetting, resistant to boiling water, and superior color dispersion.

B-609

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Fast curing, high hardness, scratch resistance, and chemical resistance.

B-615A

Aliphatic polyurethane acrylate

Fast curing, excellent toughness, wear resistance, and chemical resistance.

B-619W

Aliphatic polyurethane acrylate

Fast curing, high hardness, excellent toughness, wear resistance, and chemical resistance.

B-6380N

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Excellent adhesion to plastics, strong hiding power, and improved paint film appearance.

B-919B

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Matte

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B-572

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B-650A

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B-868

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B-868H

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B-6063

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B-6210

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B-6263

Special functional group acrylate

Fast curing, high build, boil-resistant, and excellent toughness.

B-916

Aliphatic polyurethane acrylate

Low viscosity, solvent resistance, chemical resistance, and steel-wool resistance.

B-919B

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Fast curing, high hardness, excellent toughness, and superior chemical and wear resistance.

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B-910A2

Aliphatic polyurethane acrylate

Low viscosity, yellowing resistance, chemical resistance, and steel-wool resistance.

B-916

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Low viscosity, solvent resistance, chemical resistance, and steel-wool resistance.

B-919B

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Fast curing, high hardness, excellent toughness, and superior chemical and wear resistance.

Oil-resistant pen

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B-868

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B-560

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B-151

Modified epoxy acrylate

Low halogen, yellowing-resistant, excellent plating performance, and strong adhesion.

B-160D

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B-296

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Fast curing, chemical resistance, yellowing resistance, impact resistance

B-431

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Yellowing-resistant, excellent wettability, low viscosity, fast curing

Monomer Recommendation

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BM3231 (TMPTA)

Trimethylolpropane triacrylate

High crosslink density, high hardness, high gloss, and excellent wear resistance.

BM3235 (PET3A)

Pentaerythritol triacrylate

Fast curing, high crosslink density, high hardness, and chemical resistance.

BM3380 (3EO-TMPTA)

Pentaerythritol triacrylate

More flexible and less irritating than TMPTA.

BM4241 (DiTMPTA-80)

Bis(2,3-dihydroxypropyl) tetraacrylate

High crosslink density, high hardness, chemical and wear resistance, and water resistance.

BM4242 (Di-TMPTA)

Bis-trimethylolpropane tetraacrylate

High crosslink density, high hardness, chemical and wear resistance, and water resistance.

BM6261 (DPHA-80)

Dipentaerythritol hexaacrylate

High crosslink density, high hardness, chemical and wear resistance, and water resistance.

BM6263 (DPHA-90)

Dipentaerythritol hexaacrylate

High crosslink density, high hardness, chemical and wear resistance, and water resistance.

 

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