Solutions for Defects in UV Wood Coatings (9)


In the wood coatings industry, UV wood coatings have become the preferred choice for many manufacturers due to their rapid curing, environmental friendliness, and high efficiency. However, in practical applications, these coatings often encounter several undesirable issues, particularly poor curing that leads to brittle film formation, which severely compromises both the aesthetic appeal and functional performance of the finished products. This article provides a detailed discussion of solutions to the problem of brittle UV wood coating films, helping manufacturers effectively address this challenge.

I. Precise Regulation of Solidified Energy

Excessive UV energy is the primary cause of brittle paint films. When the energy exceeds the critical threshold specified in the coating formulation, the crosslink density becomes excessively high, resulting in an over-dense three-dimensional network that severely restricts chain segment mobility. Consequently, the film loses its ability to absorb and dissipate impact energy, becoming rigid and fragile. It is recommended to precisely adjust the UV lamp power, irradiation distance, and conveyor speed based on the coating properties and film thickness, so as to keep the curing energy within an appropriate range. Regularly use an energy meter to monitor the output energy of the lamps and prevent over-curing caused by energy fluctuations. For highly reactive coatings, consider reducing the energy level or employing multiple low-energy exposures to strike a balance between crosslink density and flexibility.

II. Effective Control of Shrinkage Stress

UV curing is the rapid transformation of liquid monomers into a solid polymer, accompanied by volumetric shrinkage. When a single coat is applied too thickly, the resulting shrinkage cannot be compensated by flow within the coating film, leading to substantial tensile internal stresses. Even minor external forces can then trigger cracking. Therefore, the thickness of each individual coat should be carefully controlled in accordance with the coating’s properties. For applications requiring thick coatings, multiple thin coats are preferable to a single thick coat; each coat must be fully cured before the next is applied, allowing the shrinkage stresses to be relieved layer by layer.

When the shrinkage and flexibility of the primer and topcoat are mismatched, shear stresses develop at the interface, which can readily lead to brittle cracking of the topcoat. It is therefore essential to select a coating system with good compatibility to ensure that the shrinkage and elastic modulus of the primer and topcoat are well matched. In the design of the coating system, a combination of a flexible primer and a tough topcoat can be employed: the primer absorbs a portion of the stress, thereby reducing the load on the topcoat.

III. Scientific Design of Coating Formulations

At the formulation level, brittle paint films often result from an excessive proportion of rigid components and an insufficient proportion of flexible components, or from an overabundance of crosslinking agents that leads to overly dense crosslinking points. To address this, it is advisable to select resin systems with excellent flexibility, such as polyester acrylates or aliphatic polyurethane acrylates, which exhibit low shrinkage and superior flexibility. In formulation design, it is important to strike a proper balance between rigid and flexible monomers to avoid excessive crosslinking. For coatings requiring high hardness, toughness can be improved—without significantly compromising hardness—by incorporating toughening agents or elastomeric microspheres.

IV. Rational Matching of Coating Systems

In multi-layer coating systems, performance compatibility among the individual coats is critical. A significant mismatch in flexibility between the topcoat and the primer can lead to stress concentration at the interface, resulting in cracking. It is therefore recommended to select compatible, well-matched products with a reasonable performance gradient within the same coating system. For areas prone to cracking or for substrates with inherent brittleness, flexible additives can be incorporated into the primer to create a gradient structure in which flexibility decreases from the substrate outward, thereby effectively relieving internal stresses. During coating process design, sufficient consideration should be given to subsequent processing requirements, and an adequate margin of flexibility should be built in from the outset.

V. Conclusion

The issue of brittle paint films caused by inadequate curing of UV wood coatings is complex and challenging, requiring a comprehensive solution that addresses multiple factors. By precisely controlling UV energy, optimizing the coating application process, adjusting the coating formulation, and adopting advanced equipment and technologies, the curing quality and film performance of UV wood coatings can be significantly improved. These solutions not only help resolve current challenges but also provide strong support for the sustainable development of the wood coating industry.

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Boxing Recommended Products – UV Wood Coatings

Putty primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

Sanding primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

Apply primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-02

Phosphate ester acrylate

Enhances adhesion to substrates such as metal, glass, and plastic.

B-05

Phosphate ester acrylate

Enhances adhesion to substrates such as metal, glass, and plastic.

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

B-535

Polyester acrylate

Excellent adhesion, rapid curing, good flexibility, and yellowing resistance.

B-546

Polyester acrylate

Good adhesion, fast curing, and excellent flexibility.

White primer

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

B-529

Polyester acrylate

Good adhesion, low shrinkage, and excellent resin compatibility.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

Gloss topcoat

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion

B-21C

Active amine photosensitizing promoter

Low color number, antioxidant and anti-polymerization, and enhanced curing rate

B-301

Aromatic Polyurethane Acrylate

Fast curing, good toughness, and excellent grindability.

B-302

Aromatic Polyurethane Acrylate

Fast curing, high strength, good toughness, and excellent grindability.

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-601

Aromatic Polyurethane Acrylate

High hardness, scratch resistance, chemical resistance, and excellent cost performance.

B-609

Aliphatic polyurethane acrylate

Fast curing, high hardness, scratch resistance, and chemical resistance.

B-868

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-910A2

Aliphatic polyurethane acrylate

Low viscosity, yellowing resistance, chemical resistance, and steel-wool resistance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and wear resistance.

Matte topcoat

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-21C

Active amine photosensitizing promoter

Low color number, antioxidant and anti-polymerization, and enhanced curing rate

B-328M

Aliphatic polyurethane acrylate

Low gloss, low viscosity, excellent wettability, and a pleasant hand feel.

B-328R

Aliphatic polyurethane acrylate

Low gloss, excellent matting, good wetting, and a fine, smooth, and silky hand feel.

B-333

Aliphatic polyurethane acrylate

Low viscosity, excellent matting effect, good wetting properties, and excellent flexibility.

B-572

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-650A

Aliphatic polyurethane acrylate

Low viscosity, excellent matting effect, fast curing, and good wettability.

B-868

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-910A2

Aliphatic polyurethane acrylate

Low viscosity, yellowing resistance, chemical resistance, and steel-wool resistance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and wear resistance.

Bright White Finish

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-301

Aromatic Polyurethane Acrylate

Fast curing, good toughness, and excellent grindability.

B-302

Aromatic Polyurethane Acrylate

Fast curing, high strength, good toughness, and excellent grindability.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-601

Aromatic Polyurethane Acrylate

High hardness, scratch resistance, chemical resistance, and excellent cost performance.

B-868

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and wear resistance.

Adherent

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-05

Phosphate ester acrylate

Enhances adhesion to substrates such as metal, glass, and plastic.

B-509B

Polyester acrylate

Good adhesion, good flexibility, and excellent pigment wetting.

B-531

Polyester acrylate

Good adhesion, impact resistance, excellent flexibility, and yellowing resistance.

B-535

Polyester acrylate

Excellent adhesion, rapid curing, good flexibility, and yellowing resistance.

B-546

Polyester acrylate

Good adhesion, fast curing, and excellent flexibility.

B-590

Polyester acrylate

Excellent adhesion, rapid curing, and good pigment wetting.

Filler type

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

B-529

Polyester acrylate

Good adhesion, low shrinkage, and excellent resin compatibility.

Color correction

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

Harden

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-301

Aromatic Polyurethane Acrylate

Fast curing, good toughness, and excellent grindability.

B-302

Aromatic Polyurethane Acrylate

Fast curing, high strength, good toughness, and excellent grindability.

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-601

Aromatic Polyurethane Acrylate

High hardness, scratch resistance, chemical resistance, and excellent cost performance.

B-912

Aliphatic polyurethane acrylate

Fast curing, high hardness, good toughness, and excellent chemical and wear resistance.

Matte

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-328M

Aliphatic polyurethane acrylate

Low gloss, low viscosity, excellent wettability, and a pleasant hand feel.

B-328R

Aliphatic polyurethane acrylate

Low gloss, excellent matting, good wetting, and a fine, smooth, and silky hand feel.

B-329D

Aliphatic polyurethane acrylate

Low irritation, low viscosity, excellent wettability, and a pleasant feel.

B-333

Aliphatic polyurethane acrylate

Low viscosity, excellent matting effect, good wetting properties, and excellent flexibility.

B-650A

Aliphatic polyurethane acrylate

Low viscosity, excellent matting effect, fast curing, and good wettability.

Solid-color paint

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-519

Self-curing polyester acrylate

Self-initiated photopolymerization performance

B-530

Polyester acrylate

Low viscosity, excellent hydrophobicity, thixotropy, and improved ink misting

B-560

Polyester acrylate

Fast curing and excellent pigment wetting

Yellowing resistance

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-431

Cycloaliphatic Specialty Acrylates

Yellowing resistance, excellent wettability, low viscosity, and fast curing

Dip coating

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

Roll coating

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-100

Bisphenol A epoxy acrylate

High hardness, high gloss, excellent chemical resistance, and high fullness.

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-160D

Modified epoxy acrylate

Good flexibility, yellowing resistance, and excellent adhesion.

B-163

Modified epoxy acrylate

Good flexibility, excellent pigment wetting, and strong adhesion.

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-522

Polyester acrylate

Low shrinkage, excellent flexibility, strong adhesion, and high cost-effectiveness.

Solvent-free spraying

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-251

Aromatic Polyurethane Acrylate

Fast curing, excellent flexibility, and good wetting of black ink pigments.

B-520

Polyester acrylate

Low viscosity, high gloss, excellent wettability, and cost-effective

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

LED-UV

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-21C

Active amine photosensitizing promoter

Low color number, antioxidant and anti-polymerization, and enhanced curing rate

B-241

Aliphatic polyurethane acrylate

Fast curing, excellent skin feel, and yellowing resistance.

B-27

Active amine photosensitizing promoter

Low color number, benzene-free, low odor, antioxidant and anti-polymerization

B-570

Polyester acrylate

Low viscosity, benzene-free, low odor, suitable for LED UV

B-574

Polyester acrylate

Benzene-free, low odor, and VOC levels compliant with cigarette pack standards.

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

Excimer lamp

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-241

Aliphatic polyurethane acrylate

Fast curing, excellent skin feel, and yellowing resistance.

Skin feel

Product Model/English Abbreviation

Product Name/Product Type

Product Features

B-113

Bisphenol A epoxy acrylate

High hardness, high gloss, high fullness, contains 20% TPGDA

B-165

Modified epoxy acrylate

Good flexibility and strong adhesion

B-241

Aliphatic polyurethane acrylate

Fast curing, excellent skin feel, and yellowing resistance.

B-328M

Aliphatic polyurethane acrylate

Low gloss, low viscosity, excellent wettability, and a pleasant hand feel.

B-328R

Aliphatic polyurethane acrylate

Low gloss, excellent matting, good wetting, and a fine, smooth, and silky hand feel.

B-574C

Polyester acrylate

Low viscosity, low odor, excellent wettability; suitable for LED UV.

B-868

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

B-868H

Organosilicon UV-Curable Resin

Excellent leveling, smooth finish, fast curing, and stain resistance.

Single-item recommendation

Product Model/English Abbreviation

Product Name/Product Type

Product Features

BM2223/TPGDA

Di(propylene glycol) diacrylate

Good flexibility and low volatility

BM2224/EO-HDDA

Ethoxylated 1,6-hexanediol diacrylate

Good adhesion to plastics, good dilutability, and low volatility.

BM3231/TMPTA

Trimethylolpropane triacrylate

High crosslink density, high hardness, high gloss, and excellent wear resistance.

BM3235/PET3A

Pentaerythritol triacrylate

Fast curing, high crosslink density, high hardness, and excellent chemical resistance.

BM3380/3EO-TMPTA

Tripropylene Glycol Triacrylate

More flexible and less irritating than TMPTA.

BM6261/DPHA-80

Dipentaerythritol hexaacrylate

High crosslink density, high hardness, chemical and wear resistance, and water resistance.

BM6263/DPHA-90

Dipentaerythritol hexaacrylate

High crosslink density, high hardness, chemical and wear resistance, and water resistance.

 

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